Rearrangement of sulfonamidyl radicals with hydrogen migration

  • É. I. Troyanskii
  • M. I. Lazareva
  • G. I. Nikishin
Organic Chemistry
Received:

Conclusions

  1. 1.

    One-step outlying oxidative chlorination of alkanesulfonamides by the action of the Na2S2O8-CuCl2 system via intermediate sulfonamidyl radicals gives 3- and 4-chloroalkanesulfonamides.

     
  2. 2.

    Rearrangements of sulfonamidyl radicals with H atom migration from the sulfonyl segment predominates over rearrangement with H atom migration from the amide segment.

     

Keywords

Hydrogen Migration Amide Sulfonyl Hydrogen Migration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • É. I. Troyanskii
    • 1
  • M. I. Lazareva
    • 1
  • G. I. Nikishin
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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