Synthesis of 5-bromopentanoic acid through catalytic decomposition of the hydroperoxides of cyclopentanone
Organic Chemistry
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Conclusions
A synthetic method of preparing 5-bromopentanoic acid was develope by oxidation of cyclopentanone with aqueous solutions of H2O2. Subsequent decomposition of the resulting hydroperoxide of cyclopentanone was accomplished with a catalytic quantity of copper salt in the presence of alkali bromides.
Keywords
Oxidation Copper H2O2 Aqueous Solution Bromide
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Literature cited
- 1.E. J. Corey, N. M. Weinshenker, and T. K. Schaaf, J. Am. Chem. Soc.,91, 5675 (1969).PubMedGoogle Scholar
- 2.M. Fling, F. N. Minard, and S. W. Fox, J. Am. Chem. Soc.,69, 2466 (1947).Google Scholar
- 3.G. A. Olah, R. Krepeles, and S. C. Narang, Synthesis, No. 11, 963 (1982).Google Scholar
- 4.Preparative Organic Synthesis [Russian translation], Vol. 4, Inostr. Lit., Moscow (1953), p. 312.Google Scholar
- 5.N. Milas, S. Harries, and P. Panagiotacos, J. Am. Chem. Soc.,61, 2430 (1939).Google Scholar
- 6.V. L. Antonovskii, Organic Peroxide Initiators [in Russian], Khimiya, Moscow (1972), p. 188.Google Scholar
- 7.F. Minisci, Gazz. Chim. Ital.,89, 1922 (1959).Google Scholar
- 8.Yu. V. Il'in, V. A. Plakhotnik, V. G. Glukhovtsev, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 2243 (1982).Google Scholar
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© Plenum Publishing Corporation 1989