Monomerization of dicyclopentadiene and hydrogenation of cyclopentadiene in a stream of methane over palladium-ruthenium alloy
Organic Chemistry
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Conclusions
- 1.
Methane can be used as a heat-transfer agent for the monomerization of dicyclopentadiene and as carrier gas for the hydrogenation of cyclopentadiene (CPD) to cyclopentene at membrane catalysts consisting of a palladium alloy with 9.8% of ruthenium.
- 2.
Increases in the selectivity and in the yield of cyclopentene were found during hydrogenation of CPD with hydrogen passing through the membrane catalyst compared with the delivery of a mixture of CPD vapor and hydrogen at the same catalyst.
Keywords
Hydrogenation Methane Palladium Ruthenium Cyclopentene
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Literature cited
- 1.V. S. Smirnov, M. M. Ermilova, N. V. Kokoreva, and V. M. Gryaznov, Dokl. Akad. Nauk SSSR,220, 3 (1975).Google Scholar
- 2.V. S. Smirnov, V. M. Gryaznov, M. M. Ermilova, and N. V. Orekhova, Inventor's Certificate No. 508051, 23/10/1974; Byull. Izobr., No. 11 (1976).Google Scholar
- 3.B. N. Luk'yanov, M. M. Ermilova, V. S. Smirnov, V. M. Gryaznov, and M. G. Slin'ko, Sixth All-Union Conference on the Simulation of Chemical and Petrochemical Processes and Reactors [in Russian], Vol. 3, Dzerzhinsk (1977), p. 200.Google Scholar
- 4.K. P. Lavrovskii, L. M. Brodskii, A. N. Rumyantsev, V. P. Bulychev, and V. N. Timkin, Neftekhimiya,5, 520 (1965).Google Scholar
- 5.J. R. Bernard, Can Hoang-Yan, and S. J. Teichner, J. Chim. Phys. Phys. Chim. Biol.,74, 475 (1977).Google Scholar
- 6.H. Sakamoto, K. Takasaki, Y. Hereho, and T. Imoto, J. Appl. Chem. Biotechnol.,24, 759 (1977).Google Scholar
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© Plenum Publishing Corporation 1980