Mechanism of the synergistic action of mixtures of metal dithiocarbamates with thiuram bisulfide in the inhibition of the oxidation of hydrocarbons

  • A. N. Zverev
  • V. G. Vinogradova
  • Z. K. Maizus
Physical Chemistry
Received:

Conclusions

  1. 1.

    A phenomenon of synergism has been established in the inhibition of the initiated oxidation (75°C) and autooxidation (120°C) of ethylbenzene by mixtures of copper and nickel bis(N,N-diethyldithiocarbamates) with thiuram disulfide (TDS).

     
  2. 2.

    The synergistic effect in such systems is due to the regeneration of the dithiocarbamates of copper and nickel under the action of TDS.

     

Keywords

Oxidation Copper Nickel Hydrocarbon Disulfide 
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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • A. N. Zverev
    • 1
  • V. G. Vinogradova
    • 1
  • Z. K. Maizus
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscow

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