A study was made of the telomerization of methyl acrylate and methyl methacrylate with tetrachloropropane, initiated by the systems: Fe(CO)5 + dimethylformamide; or Fe(CO)5 + dimethylaniline. With a threefold excess of the telogen this reaction leads to a mixture of telomer homologs with the structure: ClCH2CH2CCl2(CH2CXCO2CH3)nCl and CLCH2CH2CCL2(CH2CXCO2CH3)2H, where X=H; CH3; n=1–3.
A study was made of the catalytic reduction of the obtained telomers with hydrogen over Pd/Ba · SO4.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
E. Ts. Chukovskaya, N. A. Kuz'mina, and R. Kh. Freidlina, Izv. Akad. NaukSSSR, Ser. Khim., 1198 (1969); 2343 (1970).
E. Os. Chukovskaya, N. A. Kuz'mina, and R. Kh. Freidlina, Dokl. Akad. NaukSSSR,188, 1073 (1969).
R. Ka. Freidlina and B. N. Osipov, Izv. Akad. Nauk SSSR, Ser. Khim., 2837 (1971).
A. A, Kamyshova, B. N. Osipov, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 60 (1972).
A. B. Belyavsii, E. Ts. Chukovskaya, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,202, 589 (1972).
E. ós. Chukovskaya and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 468 (1972).
N. A. Kuz'mina, E. Ts. Chukovskaya, M. A. Rozhkova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 961 (1972).
E. Ts. Chukovskaya, N. A. Kuz'mina, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 2110 (1972).
A. M. Nesmeyanov, L. I. Zakharkin, and T. A. Kost, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 660 (1955).
A. Rieche, A. Martini, E. Gründemann, and S. Schelenz, Monatsber. Deut. Akad. Wiss. Berlin,6, 183 (1964).
A. I. Vogel, J. Chem.Soc., 638 (1948).
F. Minisci and U. Pallini, Gazz. Chim. Ital.,90, 1299 (1960);91, 1030 (1961).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1782–1788, August, 1973.
About this article
Cite this article
Chukovskaya, E.T., Rozhkova, M.A. & Freidlina, R.K. Telomerization of methyl ackylate and methyl methacrylate with 1,1,1,3-tetrachloropropane, initiated by iron Pentacarbonyl and a nucleophilic reagent. Russ Chem Bull 22, 1729–1733 (1973). https://doi.org/10.1007/BF00932103