Cyclization of 3-methoxy-Δ1,3,5,(10)-8,14-secoestratriene-14,17-dione

  • S. N. Ananchenko
  • R. N. Chigir
  • I. V. Torgov
Organic and Biological Chemistry
Received:

Conclusions

Depending on the conditions, 3-methoxy-Δ1,3,5(10)-8,14-secoestratriene-14,17-dione (III) under the influence of acid agents is cyclized to estradiol, equilenol, 18-norequilenane, and cyclopentanophenanthrene derivatives. As a result, the spatial factor determines the course of the reaction even if the Δ9(11)-double bond, which activates the H atoms at C7, is absent.

Keywords

Double Bond Estradiol Dione Spatial Factor Acid Agent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • S. N. Ananchenko
    • 1
  • R. N. Chigir
    • 1
  • I. V. Torgov
    • 1
  1. 1.M. M. Shemyakin Institute of the Chemistry of Natural CompoundsAcademy of Sciences of the USSRUSSR

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