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Reactions of (1,5-cyclooctadiene)duroquinonenickel with electron donors

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Conclusions

Electron transfer from the reducing agent to the complex occurs when the electron donors, sodionaphthalene and sodiomalonic ester, act on (1,5-cyclooctadiene)duroquinonenickel, with the formation of the [(C8H12)(DQ)Ni]· anion radicals, which proved to be thermally less stable and more reactive than the anion radicals of bis(duroquinone)nickel.

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Literature cited

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2320–2322, October, 1975.

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Nesmeyanov, A.N., Isaeva, L.S. & Peganova, T.A. Reactions of (1,5-cyclooctadiene)duroquinonenickel with electron donors. Russ Chem Bull 24, 2203–2205 (1975). https://doi.org/10.1007/BF00929757

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Keywords

  • Ester
  • Nickel
  • Electron Transfer
  • Electron Donor
  • Anion Radical