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Addition of ω-Carboxyalkyl radicals to olefins, synthesis of DI- and trigarboxylic acids

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Conclusions

  1. 1.

    The 1,2,4-butane- and 1,2,5-pentanetricarboxylic acids were obtained via the addition of theβ-carboxyethyl andγ-carboxypropyl radicals to maleic acid.

  2. 2.

    Some g10 and C14 unsaturated dicarboxylic acids were synthesized by the addition ofβ-carboxyethyl radicals to butadiene. The relation between the yield of the products and the ratio of the reactants was determined.

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Literature cited

  1. 1.

    G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 825 (1973).

  2. 2.

    G. I. Nikishin, E. K. Starostin, B. A. Golovin, and E. D. Lubuzh, Izv. Akad. Nauk SSSR, Ser. Khim., 327 (1972).

  3. 3.

    G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 2060 (1971).

  4. 4.

    J. K. Kochi and F. F. Rust, J. Am. Chem. Soc.,83, 2017 (1961).

  5. 5.

    V. Karnozhitskii, Organic Peroxides [Russian translation], IL (1961), p. 66.

  6. 6.

    K. Weigand and G. Hilgetag, Experimental Methods in Organic Chemistry [Russian translation], Khimiya (1968), p. 32.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1557–1560, July, 1974.

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Starostin, E.K., Golovin, B.A. & Nikishin, G.I. Addition of ω-Carboxyalkyl radicals to olefins, synthesis of DI- and trigarboxylic acids. Russ Chem Bull 23, 1476–1478 (1974). https://doi.org/10.1007/BF00929656

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Keywords

  • Maleic Acid
  • Dicarboxylic Acid
  • Butadiene
  • Unsaturated Dicarboxylic Acid