The conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on the Na forms of zeolites of types A, X, Y, and L, as well as chabazite, erionite, and mordenite, in a batch microreactor has been investigated.
The conversion products of cyclohexene are cyclohexane and methylcyclopentarne. The greatest activity in this process is displayed by mordenite.
1,4-Cyclohexadiene is converted into 1,3-cyclohexadiene, cyclohexene, and benzene, the latter forming in dehydrogenation and disproportionation reactions. Zeolite NaY displays the greatest dehydrogenating activity among the zeolites investigated.
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Kharlamov, V.V., Starostina, T.S. & Minachev, K.M. Conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on Na forms of zeolites. Russ Chem Bull 27, 1818–1822 (1978). https://doi.org/10.1007/BF00929229