Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on Na forms of zeolites

  • 35 Accesses

Conclusions

  1. 1.

    The conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on the Na forms of zeolites of types A, X, Y, and L, as well as chabazite, erionite, and mordenite, in a batch microreactor has been investigated.

  2. 2.

    The conversion products of cyclohexene are cyclohexane and methylcyclopentarne. The greatest activity in this process is displayed by mordenite.

  3. 3.

    1,4-Cyclohexadiene is converted into 1,3-cyclohexadiene, cyclohexene, and benzene, the latter forming in dehydrogenation and disproportionation reactions. Zeolite NaY displays the greatest dehydrogenating activity among the zeolites investigated.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    Kh. M. Minachev, O. K. Shchukina, M. A. Markov, and R. V. Dmitriev, Neftekhimiya,8, 37 (1968).

  2. 2.

    K. V. Topchieva, O. L. Shakhnovskaya, and E. N. Rosolovskaya, Kinet. Katal.,10, 1381 (1969).

  3. 3.

    V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, and Kh. M. Minachev, in: All-Union Conference on the Mechanism of Heterogeneous Catalytic Reactions [in Russian], Moscow (1974), Preprint 41.

  4. 4.

    Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, T. A. Isakova, and É. É. Senderov, Izv. Akad. Nauk SSSR, Ser. Khim., 1737 (1969).

  5. 5.

    Kh. M. Minachev, V. I. Garanin, V. V. Kharlamov, and M. A. Kapustin, Izv. Akad. Nauk SSSR, Ser. Khim., 1554 (1974).

  6. 6.

    R. A. Karakhanov, V. I. Garanin, V. V. Kharlamov, M. A. Kapustin, B. B. Blinov, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 445 (1975).

  7. 7.

    F. A. Chernyshkova, D. V. Mushenko, and L. A. Blandina, Nef tekhimiya,14, 188 (1974).

  8. 8.

    T. Yashima, H. Suzuki, and N. Hara, J. Catal.,33, 486 (1974).

  9. 9.

    Kh. M. Minachev, D. B. Tagiev, and V. V. Kharlamov, Izv. Akad. Nauk SSSR, Ser. Khim., 1931 (1977).

  10. 10.

    A. A. Kubasov, A. N. Ratov, K. V. Topchieva, and L. V. Vishnevskaya, Vestn. Mosk. Univ., Ser. Khim., No. 4, 406 (1970).

  11. 11.

    F. G. Ciapetta, R. M. Dobres, and R. W. Baker, in: Catalysis in the Petrochemical and Petroleum-Refining Industries [Russian translation], Vol. 2 (1961), p. 533.

  12. 12.

    U. M. Kurkchi, V. I. Garanin, and Kh. M. Minachev, Kinet. Katal.,9, 571 (1968).

  13. 13.

    D. W. Basset and H. W. Habgood, J. Phys. Chem.,64, 769 (1960).

  14. 14.

    V. V. Kharlamov, V. I. Garanin, D. B. Tagiev, and Kh. M. Minachev, Izv. Akad. Nauk SSSR, Ser. Khim., 2406 (1975).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2065–2070, September, 1978.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Kharlamov, V.V., Starostina, T.S. & Minachev, K.M. Conversion of cyclohexane, cyclohexene, and 1,4-cyclohexadiene on Na forms of zeolites. Russ Chem Bull 27, 1818–1822 (1978). https://doi.org/10.1007/BF00929229

Download citation

Keywords

  • Benzene
  • Zeolite
  • Cyclohexene
  • Dehydrogenation
  • Disproportionation