Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Derivatives of N-α-nitroalkylhydrazines 5. UV spectra and dissociation constants for certain N-α-polynitroalkylhydrazine derivatives

  • 20 Accesses

Conclusions

  1. 1.

    Interaction between the atoms and groups in the molecule leads to an anomalous positioning of the absorption maxima in the spectra of the N-α-polynitroalkylhydrazine anions.

  2. 2.

    The acidity of the N-α-polynitroalkylhydrazine derivatives is three orders higher than that of the corresponding gem-dinitroalkanes.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    V. I. Markovskii, G. A. Marchenko, S. S. Novikov, and V. I. Slovetskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2838 (1975).

  2. 2.

    S. S. Novikov, G. A. Marchenko, V. I. Slovetskii, and V. I. Markovskii, Dokl. Akad. Nauk SSSR,221, 1341 (1975).

  3. 3.

    S. S. Novikov, V. I. Slovetskii, S. A. Shevelev, and A. A. Fainzel'berg, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 598 (1962).

  4. 4.

    M. Protiva, Laboratory Procedures in Organic Chemistry [Russian translation], Mir (1966), p. 591.

  5. 5.

    V. I. Slovetskii, V. A. Shlyapochnikov, S. A. Shevelev, A. A. Fainzel'berg and S. S. Novikov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 330 (1961); V. I. Slovetskii, A. A, Fainzel'berg, V. I. Gulevskaya, and S. S. Novikov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 683 (1961).

  6. 6.

    M. Kamlet and D. Glover, Tetrahedron Lett., No. 27, 17 (1960); J. Org. Chem.,27, 537 (1962).

  7. 7.

    V. I. Slovetskii, S. A. Shevelev, A. A. Fainzel'berg, and S. S. Novikov, Zh. Vses. Khim. O-va im. D. I. Mendeleeva,6, 707 (1961).

  8. 8.

    J. Armand, Bull. Soc. Chim. France, 3246 (1965).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1534–1537, July, 1977.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Vorob'eva, V.V., Slovetskii, V.I., Novikov, S.S. et al. Derivatives of N-α-nitroalkylhydrazines 5. UV spectra and dissociation constants for certain N-α-polynitroalkylhydrazine derivatives. Russ Chem Bull 26, 1408–1411 (1977). https://doi.org/10.1007/BF00928516

Download citation

Keywords

  • Acidity
  • Absorption Maximum
  • Dissociation Constant
  • Anomalous Position