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Glycidyl esters of phosphorus acids and their properties

Communication 5. Reaction of dialkyl glycidyl phosphates with diethylamine, ethyl alcohol, and acetic anhydride

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Conclusions

  1. 1.

    The reaction of dialkyl glycidyl phosphates with diethylamine, ethyl alcohol or acetic anhydride respectively gave the β-hydroxy-γ-diethylaminopropyl, β-hydroxy-γ-ethoxypropyl and β,γ-diacetoxypropyl dialkyl phosphates.

  2. 2.

    In the case of ethyl alcohol the epoxide ring is opened on the side of the primary carbon atom.

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Literature cited

  1. 1.

    N. I. Rizpolozhenskii, L. V. Stepashkina, and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 2013.

  2. 2.

    M. S. Malinovskii, Olefin Oxides and Their Derivatives [in Russian], Goskhimizdat (1961), pp. 195, 282.

  3. 3.

    M. M. Smirnova and N. N. Lebedev, Tr. Mosk. Khim. -Tekhnol. Inst., 1963, No. 42, 84.

  4. 4.

    T. I. Temnikova, Course in Theoretical Principles of Organic Chemistry [in Russian], Goskhimizdat (1962), p. 489.

  5. 5.

    T. Modro and J. Sokolowskii, Bull. Acad. Polon. Sci., Classe (III), 13, 687 (1965).

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    J. R. Cox and F. M. Westheimer, J. Am. Chem. Soc.,80, 5441 (1958).

  7. 7.

    G. M. Kosolapoff, Organophosphorus Compounds, New York-London (1950), p. 258.

  8. 8.

    N. I. Rizpolozhenskii, Dissertation [in Russian], Kazan (1950).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2585–2589, November, 1973.

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Stepashkina, L.V., Rizpolozhenskii, N.I. Glycidyl esters of phosphorus acids and their properties. Russ Chem Bull 22, 2517–2520 (1973). https://doi.org/10.1007/BF00926408

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Keywords

  • Alcohol
  • Phosphate
  • Acetic
  • Ester
  • Phosphorus