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Glycidyl esters of phosphorus acids and their properties

Communication 5. Reaction of dialkyl glycidyl phosphates with diethylamine, ethyl alcohol, and acetic anhydride

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  1. 1.

    The reaction of dialkyl glycidyl phosphates with diethylamine, ethyl alcohol or acetic anhydride respectively gave the β-hydroxy-γ-diethylaminopropyl, β-hydroxy-γ-ethoxypropyl and β,γ-diacetoxypropyl dialkyl phosphates.

  2. 2.

    In the case of ethyl alcohol the epoxide ring is opened on the side of the primary carbon atom.

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Literature cited

  1. 1.

    N. I. Rizpolozhenskii, L. V. Stepashkina, and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 2013.

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    M. S. Malinovskii, Olefin Oxides and Their Derivatives [in Russian], Goskhimizdat (1961), pp. 195, 282.

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    M. M. Smirnova and N. N. Lebedev, Tr. Mosk. Khim. -Tekhnol. Inst., 1963, No. 42, 84.

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    T. I. Temnikova, Course in Theoretical Principles of Organic Chemistry [in Russian], Goskhimizdat (1962), p. 489.

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    T. Modro and J. Sokolowskii, Bull. Acad. Polon. Sci., Classe (III), 13, 687 (1965).

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    J. R. Cox and F. M. Westheimer, J. Am. Chem. Soc.,80, 5441 (1958).

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    G. M. Kosolapoff, Organophosphorus Compounds, New York-London (1950), p. 258.

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    N. I. Rizpolozhenskii, Dissertation [in Russian], Kazan (1950).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2585–2589, November, 1973.

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Stepashkina, L.V., Rizpolozhenskii, N.I. Glycidyl esters of phosphorus acids and their properties. Russ Chem Bull 22, 2517–2520 (1973).

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  • Alcohol
  • Phosphate
  • Acetic
  • Ester
  • Phosphorus