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MBr-AlBr3-solv systems at 25°

Conclusions

  1. 1.

    The isotherms of MBr-AlBr3-Et2O (M=Na, K, Rb) at 25° are characterized by the crystallization branches of MBr and the AlBr3·Et2O etherate. The successive crystallization of AlBr3·Et2O, CsAlBr4 and CsBr was established in the CsBr-AlBr3-Et2O system at 25°.

  2. 2.

    The isotherm of KBr-AlBr3-C7H8 at 25° has the crystallization branches of Al2Br6·C7H8, KAl2Br7, KAlBr4, and KBr. A stratification region and the crystallization fields of Al2Br4·C7H8, Rb(Cs)Al2Br7 and Rb(Cs)Br were established for the Rb(Cs)Br-AlBr3-C7H8 systems.

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Literature cited

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    A. E. Pruntsev, S. M. Arkhipov, and V. I. Mikheeva, Izv. Akad. Nauk SSSR, Ser. Khim., 2648 (1972).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2810–2811, December, 1973.

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Mikheeva, V.I., Arkhipov, S.M. & Pruntsev, A.E. MBr-AlBr3-solv systems at 25°. Russ Chem Bull 22, 2746–2747 (1973). https://doi.org/10.1007/BF00926158

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Keywords

  • Crystallization
  • Stratification
  • Et2O
  • CsBr
  • AlBr3