Reaction of acyl isocyanates with aldehydes

  • B. A. Arbuzov
  • N. N. Zobova
  • O. V. Sofronova
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Conclusions

  1. 1.

    Aromatic aldehydes react with acyl isocyanates to give the corresponding substituted acylazomethines.

     
  2. 2.

    Aliphatic aldehydes react with trichloroacetyl isocyanate to give substituted acyl carbamates, and the trichloroacetamide of 2,2-dimethylaldo-3-propanoic acid in the case of isobutyraldehyde.

     

Keywords

Aldehyde Isocyanate Carbamate Aromatic Aldehyde Aliphatic Aldehyde 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

  1. 1.
    R. Graf, Ann. Chem.,661, 111 (1963).Google Scholar
  2. 2.
    K. Claus, H. J. Friedrich, and H. Jensen, Ann. Chem.,1974, 561.Google Scholar
  3. 3.
    J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy [Russian translation], Vol. 2, Mir (1968), p. 96.Google Scholar
  4. 4.
    R. Brehme and H. E. Nikolajewski, Tetrahedron,25, 1159 (1969).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • B. A. Arbuzov
    • 1
  • N. N. Zobova
    • 1
  • O. V. Sofronova
    • 1
  1. 1.V. I. Ul'yanov-Lenin Kazan State UniversityUSSR

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