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A study by PMR methods of exchange between trimethyltin chloride and trimethyltin mercaptides in toluene solution

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Conclusions

  1. 1.

    PMR methods have been used to show that the rate of exchange in the (CH3)3SnCl+ (CH3)3SnSR system in toluene solution varies inversely with the temperature.

  2. 2.

    At room temperature and below, the rate of exchange depends on the nature of the R radical, increasing in the order: 2,6-(CH3)2C6H3; 3,4,5-Cl3C6H2 < 3-ClC6H4 < C6H5 < 4-(CH3)2NC6H4 < CH3.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 324–327, February, 1979.

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Korniets, E.D., Rokhlina, E.M., Fedorov, L.A. et al. A study by PMR methods of exchange between trimethyltin chloride and trimethyltin mercaptides in toluene solution. Russ Chem Bull 28, 297–300 (1979). https://doi.org/10.1007/BF00925871

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Keywords

  • Chloride
  • Toluene
  • Toluene Solution
  • Trimethyltin
  • Mercaptide