Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Complex compounds of tetraalkylammonium perchlorates with aluminum borohydride

  • 23 Accesses

Conclusions

  1. 1.

    Complex compounds with the composition R4N[(ClO4)Al (BH4)3], where R = CH3, C2H5, and C4H9, were obtained by the direct interaction of aluminum borohydride with tetraalkylammonium perchlorate.

  2. 2.

    According to the data of the IR spectra, the nature of the bond of the BH4 groups to aluminum in the anion [(ClO4)Al (BH4)4] is the same as in the anion Al (BH4) 4 . The perchlorato group is monodentately bonded to the Al atom, as in the anion [Al(ClO4)6 .

  3. 3.

    The complex compounds R4N (ClO4)Al(BH4)3] are stable at ∼20°, but are sensitive to mechanical influence. The tetrabutylammonium complex decomposes slowly in the interval 100–200° with the liberation of diborane and hydrogen.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    D. G. Lemesheva and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1877 (1969).

  2. 2.

    D. G. Lemesheva, Dissertation [in Russian], Moscow (1972).

  3. 3.

    Z. K. Nikitina, A. I. Karelin, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 723 (1973),

  4. 4.

    V. Ya. Rosolovskii, Dissertation [in Russian], Moscow (1969).

  5. 5.

    K. V. Titova and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2174 (1974).

  6. 6.

    H. J. Schlesinger, H. C. Brown, and E. R. Hyde, J. Amer. Chem. Soc.,75, 209 (1953).

  7. 7.

    L. V. Titov, E. R. Eremin, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1480 (1972).

  8. 8.

    L. V. Titov, L. A. Gavrilova, E. R. Eremin, S. S. Mishchenchuk, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1354 (1971).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheakaya, No. 2, pp. 258–260, February, 1975.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Titova, K.V., Titov, L.V., Eremin, E.R. et al. Complex compounds of tetraalkylammonium perchlorates with aluminum borohydride. Russ Chem Bull 24, 198–200 (1975). https://doi.org/10.1007/BF00925752

Download citation

Keywords

  • Hydrogen
  • Aluminum
  • Perchlorate
  • Direct Interaction
  • Borohydride