Photochemical thiylation of Si-methoxy-substituted 1, 2-disilylethylenes

  • M. G. Voronkov
  • L. V. Tsvetaeva
  • M. V. Sigalov
  • Z. I. Mikhailov
  • N. F. Chernov
  • O. G. Yarosh
  • V. A. Pestunovich
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Conclusions

  1. 1.

    A number of new sulfur-containing organosilicon monomers was synthesized by the reaction of 1,2-bis(alkylmethoxysilyl)- and 1-(trimethylsilyl)-2-(methylmethoxysilyi)ethylenes with mercaptans and thioacetic acid.

     
  2. 2.

    Based on the NMR spectral data, the 1-(trimethylsilyl)-2-(methylmethoxysilyl)ethylenes form two isomeric adducts in a 1∶1 ratio.

     

Keywords

Ethylene Adduct Spectral Data Trimethylsilyl Mercaptan 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

  1. 1.
    N. V. Komarov, O. G. Yarosh, L. P. Vakhrushev, and N. F. Chernov, Zh. Obshch. Khim.,40, 1171 (1970).Google Scholar
  2. 2.
    N. V. Komarov, Z. I. Mikhailov, O. G. Yarosh, L. P. Vakhrushev, N. F. Chernov, and L. F. Ul'yanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2581 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • L. V. Tsvetaeva
    • 1
  • M. V. Sigalov
    • 1
  • Z. I. Mikhailov
    • 1
  • N. F. Chernov
    • 1
  • O. G. Yarosh
    • 1
  • V. A. Pestunovich
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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