The kinetic isotope effect KD/KT was measured during acid hydrogen exchange in π-C5H5-(CO)2Fe-σ-CH2C6H5. The obtained KD/KT value testifies in support of the generality of the mechanisms of hydrogen exchange in the benzene ring of this complex and in other derivatives of the benzene series.
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F. S. Yakushin, V. N. Setkina, E. A. Yakovleva, A. I. Shatenshtein, and D. N. Kursanov, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 206.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 221–222, January, 1979.
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Orlova, T.Y., Yakushin, F.S. & Setkina, V.N. Kinetic isotope effect during acid hydrogen exchange in σ-benzyl-π-cyclopentadienyliron dicarbonyl. Russ Chem Bull 28, 207–208 (1979). https://doi.org/10.1007/BF00925428
- Benzene Ring
- Isotope Effect
- Hydrogen Exchange