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Kinetic isotope effect during acid hydrogen exchange in σ-benzyl-π-cyclopentadienyliron dicarbonyl

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Conclusions

The kinetic isotope effect KD/KT was measured during acid hydrogen exchange in π-C5H5-(CO)2Fe-σ-CH2C6H5. The obtained KD/KT value testifies in support of the generality of the mechanisms of hydrogen exchange in the benzene ring of this complex and in other derivatives of the benzene series.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 221–222, January, 1979.

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Orlova, T.Y., Yakushin, F.S. & Setkina, V.N. Kinetic isotope effect during acid hydrogen exchange in σ-benzyl-π-cyclopentadienyliron dicarbonyl. Russ Chem Bull 28, 207–208 (1979). https://doi.org/10.1007/BF00925428

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Keywords

  • Hydrogen
  • Benzene
  • Benzene Ring
  • Isotope Effect
  • Hydrogen Exchange