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Certain reactions of tris(α,α,ω-trihydroperfluoroalkyl) phosphites

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Conclusions

Certain properties of tris(1,1,3-trihydroperfluoropropyl), tris(1,1,5-trihydroperfluoropentyl), and tris(1,1,7-trihydroperfluoroheptyl) phosphites were studied, and it was shown that the presence of theα,α,ω-trihydroperfluoroalkoxyl groups determines their behavior as the result of an increase in the v-acceptor and decrease in the n-donor ability of the phosphorus atom.

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Literature cited

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    A. V. Fokin, V. A. Komarov, A. F. Kolomiets, A. I. Papkin, K. I. Pasevina, T. M. Potarina, and O. V. Verenikin, Izv. Akad. Nauk SSSR, Ser. Khim., 1574 (1978).

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    A. V. Fokin, A. F. Kolomiets, V. A. Komarov, A. I. Papkin, A. A. Krolevets, and K. I. Pasevina, Izv. Akad. Nauk SSSR, Ser. Khim., 159 (1979).

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    A. Meller, M. Wechsberg, and V. Gutmann, Monatsh. Chem.,96, 388 (1965).

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    K. L. Raciorec, B. A. Merkl, and C. T. Lenk, J. Org. Chem.,27, 266 (1962).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 163–169, January, 1979.

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Fokin, A.V., Kolomiets, A.F., Komarov, V.A. et al. Certain reactions of tris(α,α,ω-trihydroperfluoroalkyl) phosphites. Russ Chem Bull 28, 152–158 (1979). https://doi.org/10.1007/BF00925414

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Keywords

  • Phosphorus
  • Phosphite
  • Phosphorus Atom