Hydrolysis of higher alkyldimethylchlorosilanes

  • K. A. Andrianov
  • B. A. Izmailov
  • V. D. Myakushev
Brief Communications
Received:

Conclusions

  1. 1.

    The hydrolysis of the higher alkyldimethylchlorosilanes, containing 6–10 carbon atoms in the alkyl radical, was studied and it was established that the hydrolysis leads to the formation of a mixture of the corresponding alkyldimethylhydroxysilanes and 1,3-dialkyl-1,1,3,3-tetramethyldisiloxanes.

     
  2. 2.

    The hydrolysis of the higher alkyldimethylchlorosilanes in the presence of ammonia, which binds the HC1 liberated during reaction, gives the corresponding alkyldimethylhydroxysilanes, whose yield increases with increase in the length of the alkyl radical attached to the silicon atom.

     

Keywords

Silicon Ammonia Hydrolysis Carbon Atom Alkyl Radical 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

  1. 1.
    K. A. Andrianov and B. A. Izmailov, Zh. Obshch. Khim.,34, 341 (1966).Google Scholar
  2. 2.
    K. A. Andrianov, B. A. Izmailov, and N. D. Petukhova, Zh. Obshch. Khim.,46, 599 (1976).Google Scholar
  3. 3.
    K. A. Andrianov and B. A. Izmailov, Izv. Akad. Nauk SSSR, Ser. Khim.,1966, 1102.Google Scholar
  4. 4.
    K. A. Andrianov and B. A. Izmailov, Izv. Akad. Nauk SSSR, Ser. Khim.,1967, 1070.Google Scholar
  5. 5.
    H. M. Bank, J. C. Saam, and J. L. Speier, J. Org. Chem.,29, 792 (1964).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • K. A. Andrianov
    • 1
  • B. A. Izmailov
    • 1
  • V. D. Myakushev
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRMoscow

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