PMR investigation of metal-proton and metal-metal exchange processes in substituted phenols and their organometallic derivatives
Physical Chemistry
Received:
- 17 Downloads
Conclusions
- 1.
A study has been made of metal-proton and metal-metal intermolecular exchange in substituted phenols and their OM derivatives in chloroform and pyridine solution.
- 2.
It has been shown that the exchange rate depends on the nature of the OM group, the electronic properties of the aromatic ring substituent, and the intramolecular coordination bonding to the o-halogen with the OM group.
Keywords
Phenol Chloroform Pyridine Exchange Rate Aromatic Ring
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Preview
Unable to display preview. Download preview PDF.
Literature cited
- 1.D. N. Kravtsov, A. S. Peregudov, E. M. Rokhlina, and L. A. Fedorov, J. Organomet. Chem.,77, 199 (1974).Google Scholar
- 2.L. A. Fedorov, D. N. Kravtsov, A. S. Peregudov, S. I. Pombrik, and E. M. Rokhlina, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 1512.Google Scholar
- 3.L. A. Fedorov, A. S. Peregudov, and D. N. Kravtsov, J. Organomet. Chem.,40, 251 (1972).Google Scholar
- 4.J. Lorberth and M. R. Kula, Chem. Ber.,97, 3444 (1964).Google Scholar
- 5.A. J. Leusink, H. A. Bidding, and J. M. Marsam, J. Organomet. Chem.,13, 155 (1968).Google Scholar
- 6.A. G. Davies, D. C. Kleinschmidt, P. R. Polan, and S. G. Vasischths, J. Chem. Soc., C1971, 972.Google Scholar
- 7.U. Folli, D. Larossi, and F. Taddei, J. Chem. Soc., Perkin Trans., 2,1973, 1284.Google Scholar
- 8.A. G. Davies and P. J. Puddephatt, J. Chem. Soc., C1967, 2663.Google Scholar
- 9.A. J. Bloodworth, J. Chem. Soc., C1973, 2051.Google Scholar
- 10.N. W. Alcock and R. E. Timms, J. Chem. Soc., A1968, 1873.Google Scholar
- 11.N. Ham and T. Mole, Prog. NMR Spectroscopy,4, 93 (1969).Google Scholar
Copyright information
© Plenum Publishing Corporation 1979