Employing dyanmic NMR, it was shown that the Z, E-isomerization ofα β-arylaminoacrylic esters in nitrobenzene and o-dichlorobenzene is accomplished by the thermal mechanism of rotation around the C=C bond.
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V. I. Bakhmutov, V. A. Burmistrov, K. K. Babievskii, V. M. Belikov, and É. I. Fedin, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2601.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2820-2822, December, 1977.
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Bakhmutov, V.I., Burmistrov, V.A., Babievskii, K.K. et al. Dynamic NMR study of rotation around carbon-carbon double bond in esters of α-nitro-β-arylaminoacrylic acids. Russ Chem Bull 26, 2610–2612 (1977). https://doi.org/10.1007/BF00924584
- Double Bond
- Thermal Mechanism