Catalytic activity of metal complexes fixed on a solid carrier. I. Palladium complexes deposited on ionites in hydrogenation reactions

  • V. Z. Sharf
  • V. D. Kopylova
  • L. P. Karapetyan
  • E. L. Frumkina
  • L. Kh. Freidlin
  • K. M. Saladze
  • V. N. Krutii
Organic Chemistry
Received:
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Conclusions

  1. 1.

    Palladium complexes deposited on vinylpyridine anionites, the phosphate cationite, and ampholytes at 20°C and under atmospheric hydrogen pressure catalyze the hydrogenation and rearrangement of the C=C bond of allylbenzene. Palladium complexes on carriers increase the rearrangement of the C=C bond more than Pd-black.

     
  2. 2.

    Palladium complexes on ionites are active in the hydrogenation of allyl alcohol, cyclopentadiene, and in the reduction of nitrobenzene.

     

Keywords

Hydrogenation Alcohol Phosphate Catalytic Activity Palladium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • V. Z. Sharf
    • 1
    • 2
    • 3
  • V. D. Kopylova
    • 1
    • 2
    • 3
  • L. P. Karapetyan
    • 1
    • 2
    • 3
  • E. L. Frumkina
    • 1
    • 2
    • 3
  • L. Kh. Freidlin
    • 1
    • 2
    • 3
  • K. M. Saladze
    • 1
    • 2
    • 3
  • V. N. Krutii
    • 1
    • 2
    • 3
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.Moscow Cooperative InstituteUSSR
  3. 3.Scientific-Research Institute of PlasticsMoscow

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