Measurements have been made of the Raman line intensities at 1600 cm−1, and electronic spectra developed for diphenyl and triphenyl derivatives of group V and VIb elements, respectively.
Neither the change in intensity of the Raman line, nor the alteration of the spectral characteristics of the long-wave UV band, can be used as measures of the degree of p-π coupling in the above derivatives, the monophenyl derivatives of group V–VI elements, or the phenyl derivatives of group VII elements.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
P. P. Shorygin, Usp. Khim.,40, 718 (1971).
E. D. Schmid and B. Brosa, Ber. Bunsenges, Phys. Chem.,75, 1334 (1971).
E. C. Lim. Spectrochim. Acta,19, 1967 (1963).
A. R. Katritzky, T. T. Tidwell, and R. D. Topson, J. Am. Chem. Soc.,90, 1757 (1968).
J. Angelli, R. T. C. Brownlee, A. R. Katritzky, R. D. Topson, and L. Jakhonton, J. Am. Chem. Soc.,91, 4500 (1969).
W. R. Cullen and R. M. Hochstrasser, J. Mol. Spectrosc.,5, 118 (1960).
G. Schaw and R. Murrey, Chem. Commun., 425 (1966).
O. A. Yakutina, G. V. Ratovskii, Yu. L. Frolov, L. M. Sergienko, and V. G. Rozinov, Teor. Eksp. Khim.,1, 515 (1971).
A. N. Rodionov, Usp. Khim.,42, 2152 (1973).
H. H. Jaffe and M. Orchin, Theory and Application of Ultraviolet Spectroscopy, London (1964), p. 498.
W. R. Cullen and B. R. Green, J. Inorg. Nucl. Chem.,27, 641 (1965).
W. Jones and Y. C. Tebby, J. Chem. Soc., Perkin Trans. 2, 1125 (1973).
A. J. Kiss and B. R. Muth, Acta Chim. Acad. Sci. Hung.,22, 397 (1960).
E. N. Tsvetkov, D. A. Bochvar, and M. I. Kabachnik, Teor. Eksp. Khim.,3, 1 (1967).
K. Kumura and S. Nagakura, Mol. Phys.,9, 117 (1965).
N. P. Borisova and L. N. Petrov, Zh. Strukt. Khim.,13, 701 (1972).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1981–1987, September, 1977.
The authors would like to thank L. A. Leites and A. N. Rodionov for a discussion of the results obtained in this work.
About this article
Cite this article
Épshtein, L.M., Zhdanova, A.N. & Kazitsyna, L.A. The problem of using UV and Raman spectra to study p-π coupling. Russ Chem Bull 26, 1836–1840 (1977). https://doi.org/10.1007/BF00924371
- Raman Spectrum
- Spectral Characteristic
- Electronic Spectrum