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The problem of using UV and Raman spectra to study p-π coupling

Conclusions

  1. 1.

    Measurements have been made of the Raman line intensities at 1600 cm−1, and electronic spectra developed for diphenyl and triphenyl derivatives of group V and VIb elements, respectively.

  2. 2.

    Neither the change in intensity of the Raman line, nor the alteration of the spectral characteristics of the long-wave UV band, can be used as measures of the degree of p-π coupling in the above derivatives, the monophenyl derivatives of group V–VI elements, or the phenyl derivatives of group VII elements.

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1981–1987, September, 1977.

The authors would like to thank L. A. Leites and A. N. Rodionov for a discussion of the results obtained in this work.

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Épshtein, L.M., Zhdanova, A.N. & Kazitsyna, L.A. The problem of using UV and Raman spectra to study p-π coupling. Russ Chem Bull 26, 1836–1840 (1977). https://doi.org/10.1007/BF00924371

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Keywords

  • Phenyl
  • Raman Spectrum
  • Spectral Characteristic
  • Electronic Spectrum
  • Diphenyl