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Ammonium perchloratoaluminates

  • Z. K. Nikitina
  • V. Ya. Rosolovskii
Inorganic Chemistry

Conclusions

  1. 1.

    The authors have investigated the reaction of aluminum chloride with solutions of ammonium perchlorate in perchloric acid in absence of oxonium perchlorate. At a molar ratio NH4:Al=1 they obtained anhydrous tetraperchloratoaluminate solvated with perchloric acid; at a ratio NH4:Al=2, (NH4)2-Al(ClO4)5 crystallizes from perchloric acid; and at NH4∶Al=3, (NH4)3(ClO4)6 crystallizes.

     
  2. 2.

    By desolvation of the tetraperchloratoaluminate solvated with perchloric acid, they have obtained NH4Al(ClO4)4 in vacuum at 50–70°C.

     

Keywords

Aluminum Chloride Ammonium Perchlorate Perchloric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • Z. K. Nikitina
    • 1
  • V. Ya. Rosolovskii
    • 1
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRChernogolovka

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