A method was developed for the preparation of trichloroallyl alcohol from methanol and tetrachloroethylene in a titanium apparatus under a pressure of 100–120 atm in the presence of CC14 (335°), CH3COC2H5 (365°) or (CH3)3COOC (CH3)3 (185°), in a yield of 35–55% when based on starting TCE and 85–90% when based on reacted TCE, with a reactor output of up to 1000 g/h liter.
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Yu. B. Vol'kenshtein, M. A. Besprozvannyi, L. K. Salamandra, L. P. Gudovich, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim.,1972, 2601.
L. K. Salamandra, Yu. B. Vol'kenshtein, M. A. Besprozvannyi, and L. P. Gudovich, Zh. Prikl. Khim.,45, 1966 (1972).
C. Walling and E. Huyser, in “Organic Reactions” [Russian translation], Vol. 13, “Mir” (1966), p. 126,
M. Tatsuo and Y. Takaari, Bull. Chem. Soc. Japan,40, 1991 (1967).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2868–2870, December, 1974.
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Salamandra, L.K., Vol'kenshtein, Y.B., Besprozvannyi, M.A. et al. Reaction of tetrachloroethylene with methanol under pressure. Russ Chem Bull 23, 2775–2777 (1974). https://doi.org/10.1007/BF00923736
- Reactor Output