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Temperature dependence of the rate of rapid reactions of proton transfer in aqueous solution

Communication 3. Reactions of protonation of nitrogen-containing bases

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Conclusions

  1. 1.

    The kinetics was studied and the activation parameters were determined for the protonation of hydrazine, hydroxylamine, ammonia, and the NH2Pt(NH3)4Cl2+cation in an aqueous solution containing the acid-base indicator dibromocresolsulfophthalein.

  2. 2.

    The increased values found for the activation energy of protonation by the hydrated proton of the N- and O-bases studied in this and previous works were interpreted within the framework of the hypothesis of the presence of a preceding equilibrium of reorganization of the solvate shell of the base.

  3. 3.

    The transfer of a proton to the bases studied from the dibromocresolsulfophthalein anion proceeds in a system of diffusion control.

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Literature cited

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Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2697–2703, December, 1974.

The authors would like to express their gratitude to O. Ya. Samoilov and R. R. Dogonadze for their useful discussion of the work.

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Vargaftik, M.N., Katsman, L.A. & Syrkin, Y.K. Temperature dependence of the rate of rapid reactions of proton transfer in aqueous solution. Russ Chem Bull 23, 2605–2610 (1974). https://doi.org/10.1007/BF00923689

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Keywords

  • Ammonia
  • Aqueous Solution
  • Hydrated
  • Activation Energy
  • Hydrazine