Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene

Conclusions

A study was made of the reaction for replacing the hydrogen atom, attached to the silicon in triorganylsilanes, by the chlorine atom when reaction is with chlorobenzene in the presence of colloidal nickel as the catalyst. A probable scheme of the reaction mechanism is given.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    Yu. I. Khudobin, B. N. Dolgov, and N. P. Kharitonov, in: Chemistry and Practical Application of Organosilicon Compounds [in Russian], Izd. AN SSSR (1961), No. 6, p. 155.

  2. 2.

    Yu. I. Khudobin, M. G. Voronkov, and N. P. Kharitonov, Izv. Akad. Nauk Latv. SSR, Ser. Khim., 598 (1967).

  3. 3.

    Yu. I. Khudobin, M. G. D'yachenko, N. P. Kharitonov, and P. A. Vasil'eva, Zh. Obshch. Khim.,38, 187 (1968).

  4. 4.

    Yu. I. Khudobin, N. A. Sergeeva, and N. P. Kharatonov, Zh. Obshch. Khim.,38, 412 (1968).

  5. 5.

    V. Bazant, V. Chvalovsky, and J. Rathhousky, Organosilicon Compounds, Prague (1965), Vol. 1, Part 1, pp. 132, 180, 237, 353, 506, 521, 558, 608, 665, 684; Vol. 2, Part 2, pp. 50, 80, 81, 125, 126.

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 856–859, April, 1974.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Khudobin, Y.I., Andreeva, N.A., Kharitonov, N.P. et al. Synthesis of triorganylchlorosilanes by catalytic reaction of triorganylsilanes with chlorobenzene. Russ Chem Bull 23, 820–822 (1974). https://doi.org/10.1007/BF00923508

Download citation

Keywords

  • Hydrogen
  • Silicon
  • Nickel
  • Chlorine
  • Hydrogen Atom