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Solvent effect on H1 and F19 NMR spectra of benzyltrifluoromethylmercury

Conclusions

  1. 1.

    For the complexes of benzyltrifluoromethylmercury with various solvents the electron-donor activity of these solvents correlates with the J (Hg199-C-H1) constant.

  2. 2.

    The J (Hg199-C-F19) constant for solutions of BzHgCF3 in these solvents is determined by the different ratio of theσ-(valence) andπ-(steric) contributions, and consequently does not characterize the change in the electron-donor activity of the solvents.

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Literature cited

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Additional information

Communication 8 in the series “Effects of the medium in NMR.” See [1] for previous communication.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1428–1430, June, 1974.

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Petrosyan, V.S., Bakhmutov, V.I. & Reutov, O.A. Solvent effect on H1 and F19 NMR spectra of benzyltrifluoromethylmercury. Russ Chem Bull 23, 1353–1355 (1974). https://doi.org/10.1007/BF00923119

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Keywords

  • Solvent Effect