Reaction of tetraethoxysilane and triethoxymethane with some α-substituted α, β-unsaturated aldehydes

  • M. G. Voronkov
  • N. A. Keiko
  • L. G. Stepanova
  • G. I. Kirillova
  • T. N. Musorina
  • I. D. Kalikhman
Brief Communications
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Conclusions

  1. 1.

    The reaction of α-halo-substituted α, β-unsaturated aldehydes with tetraethoxysilane and triethoxy-methane makes it possible to obtain their acetals in good yields.

     
  2. 2.

    The reaction of α-ethoxyacrolein with tetraethoxysilane and with triethoxymethane does not give the acetal, but instead either 2, 2-diethoxypropanal or 1,1,2,2,4,4-hexaethoxybutane.

     

Keywords

Acetal Aldehyde Good Yield Tetraethoxysilane Triethoxymethane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • M. G. Voronkov
    • 1
  • N. A. Keiko
    • 1
  • L. G. Stepanova
    • 1
  • G. I. Kirillova
    • 1
  • T. N. Musorina
    • 1
  • I. D. Kalikhman
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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