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Dipole moments of adducts of pyridine and γ-picoline with derivatives of π-allylpalladium chloride

  • O. G. Levanda
  • G. N. Kartsev
  • S. I. Ignat'eva
  • I. I. Moiseev
Physical Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    The dipole moment ofπ-allyl complexes of palladium with the composition (RC3H4PdCl)2 and RC3H4PdCl (amine) were measured.

     
  2. 2.

    The moment of theπ-allyl-palladium bond is 2–2.5 D and is directed from the allyl to the Pd, i. e., the allyl group carries a positive charge in comparison with the metal atom.

     
  3. 3.

    The observed dipole moments of binuclear complexes agree with the assumption of a disruption of the planar character of the bridge Pd2Cl2 group in solution.

     

Keywords

Chloride Pyridine Adduct Palladium Dipole Moment 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • O. G. Levanda
    • 1
    • 2
  • G. N. Kartsev
    • 1
    • 2
  • S. I. Ignat'eva
    • 1
    • 2
  • I. I. Moiseev
    • 1
    • 2
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRMoscow
  2. 2.M. V. Lomonosov Moscow Institute of Fine Chemical TechnologyUSSR

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