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Preparation of stable compound with O-Hg-Ge grouping

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  1. 1.

    The first stable compound with an O-Hg-Ge grouping was obtained by the reaction of 4,6-ditert-butyl-1,2-benzoquinone with bis(triisopropylgermyl)mercury.

  2. 2.

    A study was made of the photodecomposition of 1-triisopropylgermyloxy-2-triisopropylgermyl-mercuroxy-3,5-di-tert-butylbenzene, and also of its reaction with hydrochloric acid and ethylmercury chloride.

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Literature cited

  1. 1.

    G. A. Abakumov, E. N. Gladyshev, N. S. Vyazankin, G. A. Razuvaev, P, Ya. Bayushkin, and V. A. Muraev, J. Organometal. Chem.,64, 327 (1974).

  2. 2.

    N. S. Vasileiskaya, É. P. Oleinik, A. P. Kut'in, and D. V. Muslin, Zh. Obshch. Khim.,42, 636 (1972)

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 447–449, February, 1976.

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Bayushkin, P.Y., Gladyshev, E.N., Razuvaev, G.A. et al. Preparation of stable compound with O-Hg-Ge grouping. Russ Chem Bull 25, 431–433 (1976). https://doi.org/10.1007/BF00922496

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  • Chloride
  • Mercury
  • Hydrochloric Acid
  • Benzoquinone
  • Photodecomposition