A “trap” method has been used to identify and quantitatively determine radical products formed in a primary photochemical act.
In the photolysis of solutions of compounds with the general formula Ph3M at 300°K the quantum yield of the radical products increases substantially with increasing atomic number of the element.
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Smirnov, S.G., Rodionov, A.N., Rogozhin, K.L. et al. Investigation of the photolysis of aromatic derivatives of the group VB elements. Russ Chem Bull 25, 316–318 (1976). https://doi.org/10.1007/BF00922465
- Quantum Yield
- Atomic Number
- General Formula
- Radical Product