Advertisement

Springer Nature is making Coronavirus research free. View research | View latest news | Sign up for updates

Effect of diethylamine on polychloroalkanes containing the CHCl2CH2CCl2 group and on related compounds

  • 22 Accesses

Conclusions

  1. 1.

    A method is presented for the one-step synthesis of 1,3-dichloro-5-diethylamino-1,3-pentadiene and 1,3-dichloro-7-diethylamino-1,3-heptadiene from 1,1,3,3,5-pentachloropentane and 1,1,3,3,7-pentachloroheptane, respectively.

  2. 2.

    The reaction of polychloroalkanes containing the CHCl2CH2CCl2 grouping with diethylamine involves a dehydrochlorination stage.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    R. Kh. Freidlina and E. Ts. Chukovskaya, Synthesis, 477 (1974).

  2. 2.

    T. T. Vasil'eva, G. B. Khudyakova, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1068 (1973).

  3. 3.

    R. Kh. Freidlina, V. I. Dostovalova, E. Ts. Chukovskaya, and T. T. Vasil'eva, Zhurn. Strukt. Khim.,14, 1011 (1973).

  4. 4.

    W. R. Benson and A. E. Pohland, J. Org. Chem.,29, 385 (1964).

  5. 5.

    R. Kh. Freidlina, T. T. Vasil'eva, V. I. Dostovalova, and E. Ts. Chukovskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 2236 (1972).

  6. 6.

    N. K. Kochetkov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 991 (1953).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 850–854, April, 1976.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Vasil'eva, T.T. Effect of diethylamine on polychloroalkanes containing the CHCl2CH2CCl2 group and on related compounds. Russ Chem Bull 25, 829–832 (1976). https://doi.org/10.1007/BF00922390

Download citation

Keywords

  • Related Compound
  • Diethylamine
  • Pentadiene
  • Heptadiene