A method is presented for the one-step synthesis of 1,3-dichloro-5-diethylamino-1,3-pentadiene and 1,3-dichloro-7-diethylamino-1,3-heptadiene from 1,1,3,3,5-pentachloropentane and 1,1,3,3,7-pentachloroheptane, respectively.
The reaction of polychloroalkanes containing the CHCl2CH2CCl2 grouping with diethylamine involves a dehydrochlorination stage.
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R. Kh. Freidlina and E. Ts. Chukovskaya, Synthesis, 477 (1974).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 850–854, April, 1976.
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Vasil'eva, T.T. Effect of diethylamine on polychloroalkanes containing the CHCl2CH2CCl2 group and on related compounds. Russ Chem Bull 25, 829–832 (1976). https://doi.org/10.1007/BF00922390
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