The reaction of methyldiacetylene with aliphatic alcohols (heating on the steam bath in the presence of KOH) leads only to the cis-ethynyl vinyl ethers.
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B. P. Gusev and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim.,1964, 1318.
E. A. Él'perina, Dissertation [in Russian], Moscow (1968).
Yu. A. Zaichenko, L. N. Reshetova, and I. A. Maretina, Zh. Organ. Khim.,7, 2461 (1971).
W. E. Truce, J. A. Simms, and M. M. Boudakian, J. Am. Chem. Soc,78, 695 (1956); W. E. Truce and M. M. Boudakian, J. Am. Chem. Soc,78, 2748, 2752 (1956); S. I. Miller, J. Am. Chem. Soc.,78, 6091 (1956).
F. Bohlman, C. Arndt, and J. Starnick, Tetrahedron Lett.,1963, 1605.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 208–209, January, 1974.
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Gusev, B.P., Kucherov, V.F. Reaction of methyldiacetylene with aliphatic alcohols under alkaline catalysis conditions. Russ Chem Bull 23, 199–200 (1974). https://doi.org/10.1007/BF00922345