Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Hydrazones

Communication 41. Electrochemical reduction of certain alicyclic azines in dimethylformamide

  • 34 Accesses

Conclusions

The mechanisms of the electrochemical reduction of azines of acetaldehyde, acetophenone, benzophenone, and fluorenone in DMFA were discussed. It was shown by the ESR method that the dianion of fluorenone gives an electron to the initial molecule in solution, with the formation of two radical particles.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    H. Lund, The Chemistry of the Carbon Nitrogen Double Bond, Ed. S. Patai, Intersci. Publ., New York (1970), p. 505.

  2. 2.

    V. D. Bezuglyi and N. P. Shimanskaya, Zh. Obshch. Khimii,35, 17 (1965).

  3. 3.

    Yu. P. Kitaev, V. Kh. Ivanova, V. I. Savin, and L. I. Trifonova, Izv. Akad. Nauk SSSR, Ser. Khim., 2179 (1972).

  4. 4.

    J. Harriman and A. Maki, J. Chem. Phys.,39, 778 (1963).

  5. 5.

    R. Nicholson, J. Wilson, and M. Olmstead, Analyt. Chem.,38, 542 (1966).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 72–75, January, 1974.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Kitaev, Y.P., Ivanova, V.K., Mukhtarov, A.S. et al. Hydrazones. Russ Chem Bull 23, 64–66 (1974). https://doi.org/10.1007/BF00922313

Download citation

Keywords

  • Acetaldehyde
  • Hydrazones
  • Acetophenone
  • Benzophenone
  • Electrochemical Reduction