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Role of carbene complexes in chain initiation and propagation of double-boot redistribution reactions

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Conclusions

  1. 1.

    Catalytic decomposition of aliphatic diazo compound under the effect of tungsten chlorides leads to initiation of the chain process of opening of cycloolefins.

  2. 2.

    The possibility was shown on the example of the organotungsten compound (CH3)3SiCH2-WCl5 of using oxidation-reduction systems to generate carbene active centers at low temperatures.

  3. 3.

    Certain aspects of the chain stage of the double-bond redistribution process were examined in connection with the relative reactivity of carbene active centers.

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Literature cited

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    B. A. Dolgoplosk, K. L. Makovetsky, T. G. Golenko, Yu. V. Korshak, and E. I. Tinyakova, Eur. Polym. J.,10, 901 (1974).

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    T. G. Golenko, B. A. Dolgoplosk, K. L. Makovetskii, and I. Ya. Ostrovskaya, Dokl. Akad. Nauk SSSR,220, 863 (1975).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 1084–1089, May, 1976.

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Dolgoplosk, B.A., Makovetskii, K.L., Tinyakova, E.I. et al. Role of carbene complexes in chain initiation and propagation of double-boot redistribution reactions. Russ Chem Bull 25, 1053–1057 (1976). https://doi.org/10.1007/BF00921990

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Keywords

  • Chloride
  • Tungsten
  • Active Center
  • Carbene
  • Chain Process