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Tetraalkylammonium haloperchloratoaluminates

  • K. V. Titova
  • E. I. Kolmakova
Inorganic Chemistry

Conclusions

  1. 1.

    By direct reaction between ionic perchlorates and AlX3 (X = Cl, Br), the Cl04, group can be introduced into the coordination sphere of the aluminum atom.

     
  2. 2.

    The authors have synthesized the stable complexes R4N+[X3AlOCl03] (R = CH3, C2H5, C4, H9; X = Cl, Br). These complexes have sharp melting points, which decrease as we go from X = Cl to X = Br and from R = CH3 to R = C4H9.

     

Keywords

Aluminum Melting Point Perchlorate Coordination Sphere Stable Complex 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • K. V. Titova
    • 1
  • E. I. Kolmakova
    • 1
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRChernogolovka

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