The reaction of bis (π-allyl)dipalladium dichloride with diethylcadmium, bis(triethylgermyl)cadinium, and bis (triethylgermyl)mercury was studied. The reaction proceeds with the initial formation of the 1∶1 adduct and subsequent exchange reaction.
The decomposition of the intermediate [AllPdR] compounds depends on the nature of the E group. When R=Et the decomposition proceeds via the intermediate formation of the π-olefin complex and the subsequent liberation of ethylene. When R=Et3Ge the decomposition includes the disproportionation reaction and the radical decomposition of the disproportionation products.
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Razuvaev, G.A., Domrachev, G.A., Bychkov, V.T. et al. Reaction of bis (π-allyl)dipalladium dichloride with diethylcadmium and bis (triethylgermyl) cadmium. Russ Chem Bull 25, 1984–1986 (1976). https://doi.org/10.1007/BF00921744
- Exchange Reaction