Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Reaction of bis (π-allyl)dipalladium dichloride with diethylcadmium and bis (triethylgermyl) cadmium

Conclusions

  1. 1.

    The reaction of bis (π-allyl)dipalladium dichloride with diethylcadmium, bis(triethylgermyl)cadinium, and bis (triethylgermyl)mercury was studied. The reaction proceeds with the initial formation of the 1∶1 adduct and subsequent exchange reaction.

  2. 2.

    The decomposition of the intermediate [AllPdR] compounds depends on the nature of the E group. When R=Et the decomposition proceeds via the intermediate formation of the π-olefin complex and the subsequent liberation of ethylene. When R=Et3Ge the decomposition includes the disproportionation reaction and the radical decomposition of the disproportionation products.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    G. A. Razuvaev, G. A. Domrachev, O. N. Suvorova, and L. G. Abakumova, J. Organometall. Chem.32, 113 (1971).

  2. 2.

    G. A. Domrachev, K. G. Shal'nova, and V. A. Varyukhin, Zh. Obshch. Khim.,41, 1924 (1971).

  3. 3.

    G. A. Domrachev, K. G. Shal'nova, and V. A. Varyukhin, Izv. Akad. Nauk SSSR, Ser. Khim. 156 (1972).

  4. 4.

    G. A. Domrachev, K. G. Shal'nova, and V. A. Varyukhin, Izv. Akad. Nauk SSSR, Ser. Khim., 158 (1972).

  5. 5.

    T. Saito, Y. Uchida, A. Misono, A. Yamamoto, K. Morifuji, and S. Ikeda, J. Am. Chem. Soc.,88 5198 (1966).

  6. 6.

    G. Wilke and G. Herrmann, Angew. Chem.,78, 591 (1966).

  7. 7.

    P. M. Maitlis and F. G. A. Stone, Chem. Ind. (London), 1865 (1962).

  8. 8.

    M. Green, Organometallic Compounds, Halsted Press (1968).

  9. 9.

    G. A. Razuvaev, V. T. Bychkov, and N. S. Vyazankin, Dokl. Akad. Nauk SSSR,211, 116 (1973).

  10. 10.

    G. A. Razuvaev, V. N. Latyeva, L. I. Vishinskaya, V. T. Bychkov, and G. A. Vasilyeva, J. Organometall. Chem.,87, 93 (1975).

Download references

Author information

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2120–2122, September, 1976.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Razuvaev, G.A., Domrachev, G.A., Bychkov, V.T. et al. Reaction of bis (π-allyl)dipalladium dichloride with diethylcadmium and bis (triethylgermyl) cadmium. Russ Chem Bull 25, 1984–1986 (1976). https://doi.org/10.1007/BF00921744

Download citation

Keywords

  • Ethylene
  • Mercury
  • Cadmium
  • Adduct
  • Exchange Reaction