Photosensitivity of methylene chloride, stimulated by free radicals
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Conclusions
The direct photolysis of CH2C12 leads to the formation of HC1 and unsaturated compounds with conjugated C=C bonds. These same products are also formed under the influence of light that is not absorbed by CH2C12 (λ > 290 nm) in the presence of initiators of free radical reactions: benzoyl peroxide, benzophenone, anthraquinone, and Fe3+ chlorides.
Keywords
Methylene Chloride Peroxide Free Radical Methylene Chloride
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Literature cited
- 1.R. B. Fox and T. R. Price, J. Appl. Polymer Sci.,11, 2373 (1967).Google Scholar
- 2.
- 3.A. Weissberger, E. S. Proskauer, J. A. Riddick, and E. E. Toops, Jr., Organic Solvents [Russian translation], IL (1958).Google Scholar
- 4.G. A. Gamlen and D. O. Jordan, J. Chem. Soc., 1435 (1953).Google Scholar
- 5.A. I. Kryukov and S. A. Ivanitskaya, Ukr. Khim. Zh.,34, 3 (1968).Google Scholar
- 6.S. D. Razumovskii and G. E. Zaikov, Ozone and Its Reactions with Organic Compounds [in Russian], Nauka (1974), p. 69.Google Scholar
- 7.R. J. Fox, F. W. Evans, and M. Szwars, Trans. Faraday Soc.,57, 1915 (1961).Google Scholar
- 8.P. Sykes, A Guidebook to Mechanisms in Organic Chemistry, Halsted Press (1975).Google Scholar
- 9.J. P. Symons and A. J. Jarwood, Trans. Faraday Soc.,57, 2167 (1961).Google Scholar
- 10.J. P. Symons and A. J. Jarwood, Trans. Faraday Soc.,59, 90 (1963).Google Scholar
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© Plenum Publishing Corporation 1977