A spectrophotometric study was made of complex formation in aqueous π-allylpalladium bromide solutions in the pH range 2–14 and a bromide-ion concentration of 0–1.0 g-ion/liter.
The obtained results were interpreted within the framework of a scheme, in harmony with which the following complexes exist in aqueousπ-allylpalladium bromide solutions: C3H5PdBr 2 − , C3H5PdBr·H2O, C3H5PdBr(OH)−, C3H5Pd(OH)·H2O, C3H5Pd(OH) 2 − , C3H5Pd(H2O) 2 + . The values of the constants of the mutual transformations of these complexes were determined.
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L. A. Katsman, M. N. Vargaftik, A. P. Belov, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1071 (1971).
N. G. Satsko, A. P. Belov, I. I. Moiseev, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2591 (1971).
L. M. Zaitsev, A. P. Belov, M. N. Vargaftik, and I. I. Moiseev, Zh. Neorg. Khim.,12, 396 (1967).
L. Elding, Inorg. Chim. Acta,6, 647 (1972).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 733–736, March, 1974.
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Belov, A.P., Chubriev, Z.R., Moiseev, I.I. et al. Study of complex formation in aqueous π-allylpalladium bromide solutions. Russ Chem Bull 23, 703–705 (1974). https://doi.org/10.1007/BF00921182
- Complex Formation
- Bromide Solution
- Spectrophotometric Study
- Mutual Transformation