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Effect of composition of coordination sphere on value of constant of additional hyperfine structure of EPR spectra

Conclusions

Replacing the oxygen atoms by sulfur atoms in the coordination sphere of nitrogen-containing copper complexes leads to a substantial increase in the constant of the additional hyperfine structure from the nitrogen atoms, and consequently also to an increase in the degree of covalency of the Cu-N bonds.

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Literature cited

  1. 1.

    Yu. A. Bankovskii and A. F. Ievin'sh, Chemistry, Technology, and Application of Pyridine and Quinoline Derivatives [in Russian], Izd. AN LatvSSR, Riga (1960).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 704–706, March, 1974.

The authors thank V. I. Nefedov for taking the x-ray electronic spectra of compounds (I) and (II).

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Larin, G.M., Kolosov, V.A. Effect of composition of coordination sphere on value of constant of additional hyperfine structure of EPR spectra. Russ Chem Bull 23, 669–670 (1974). https://doi.org/10.1007/BF00921169

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Keywords

  • Oxygen
  • Nitrogen
  • Copper
  • Sulfur
  • Oxygen Atom