Replacing the oxygen atoms by sulfur atoms in the coordination sphere of nitrogen-containing copper complexes leads to a substantial increase in the constant of the additional hyperfine structure from the nitrogen atoms, and consequently also to an increase in the degree of covalency of the Cu-N bonds.
This is a preview of subscription content, log in to check access.
Buy single article
Instant access to the full article PDF.
Price includes VAT for USA
Subscribe to journal
Immediate online access to all issues from 2019. Subscription will auto renew annually.
This is the net price. Taxes to be calculated in checkout.
Yu. A. Bankovskii and A. F. Ievin'sh, Chemistry, Technology, and Application of Pyridine and Quinoline Derivatives [in Russian], Izd. AN LatvSSR, Riga (1960).
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 704–706, March, 1974.
The authors thank V. I. Nefedov for taking the x-ray electronic spectra of compounds (I) and (II).
About this article
Cite this article
Larin, G.M., Kolosov, V.A. Effect of composition of coordination sphere on value of constant of additional hyperfine structure of EPR spectra. Russ Chem Bull 23, 669–670 (1974). https://doi.org/10.1007/BF00921169
- Oxygen Atom