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79Br NQR spectra of dibromo (dialkylamino) boranes

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Conclusions

  1. 1.

    The79Br NQR spectra of a number of dibromo (dialky lamino)boranes and dibromo(diphenylamino)-borane were measured. A correlation was found to exist between the79Br NQR frequencies of the dibromoaminoboranes and the length of the hydrocarbon chain R on the nitrogen atom.

  2. 2.

    A substantial degree of double bonding of the boron-nitrogen bond exists in the dibromoaminoboranes.

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Literature cited

  1. 1.

    K. Niedenzu and J. W. Dawson, Boron-Nitrogen Compounds, Springer-Verlag (1985).

  2. 2.

    G. K. Semin, T. A. Babushkina, and G. G. Yakobson, Application of Nuclear Quadrupole Resonance [in Russian], Khimiya (1972).

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    Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Rostov. Univ. (1966).

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    A. J. Banister, N. N. Greenwood, B. P. Straugnan, and J. Walker, J. Chem. Soc., 995 (1964).

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    V. I. Spitsyn, L D. Kolli, T. G. Sevast'yanova, and E. A. Balabanova, Izv. Akad, Nauk SSSR, Ser. Khim., 2626 (1974).

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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1614–1615, July, 1976.

The authors are indebted to G. K. Semin for his assistance in the work.

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Bryukhova, E.V., Kazakov, V.P., Balabanova, E.A. et al. 79Br NQR spectra of dibromo (dialkylamino) boranes. Russ Chem Bull 25, 1529–1531 (1976). https://doi.org/10.1007/BF00920833

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Keywords

  • Nitrogen
  • Hydrocarbon
  • Double Bonding
  • Nitrogen Atom
  • Borane