The79Br NQR spectra of a number of dibromo (dialky lamino)boranes and dibromo(diphenylamino)-borane were measured. A correlation was found to exist between the79Br NQR frequencies of the dibromoaminoboranes and the length of the hydrocarbon chain R on the nitrogen atom.
A substantial degree of double bonding of the boron-nitrogen bond exists in the dibromoaminoboranes.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1614–1615, July, 1976.
The authors are indebted to G. K. Semin for his assistance in the work.
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Bryukhova, E.V., Kazakov, V.P., Balabanova, E.A. et al. 79Br NQR spectra of dibromo (dialkylamino) boranes. Russ Chem Bull 25, 1529–1531 (1976). https://doi.org/10.1007/BF00920833
- Double Bonding
- Nitrogen Atom