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Complex compounds of chlorodiphenylborine with primary amines, and n-substituted diphenylborinamides

Summary

  1. 1.

    The action of primary aliphatic amines on chlorodiphenylborine yielded complex compounds containing two molecules of addend per molecule of chloride.

  2. 2.

    Pyrolysis of the complexes of chlorodiphenylborine with methylamine, ethylamine, and isobutylamine gave the corresponding N-alky1 derivatives of diphenylborinamide.

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Literature cited

  1. [1]

    B. M. Mikhailov and N. S. Fedotov, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1956, 1511.

  2. [2]

    H. Meerwein and W. Panwitz, J. Prakt. Chem 141, 123 (1934).

  3. [3]

    B. M. Mikhailov and T. A. Shchegoleva, J. Gen. Chem., 29, 10 (1959).

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Mikhailov, B.M., Fedotov, N.S. Complex compounds of chlorodiphenylborine with primary amines, and n-substituted diphenylborinamides. Russ Chem Bull 8, 1428–1430 (1959). https://doi.org/10.1007/BF00918588

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Keywords

  • Chloride
  • Pyrolysis
  • Primary Amine
  • Complex Compound
  • Methylamine