EPR spectra of anion radicals of α,α′-azoisobutyro-dinitrile and the diethyl ester of azoacetic acid

  • A. I. Prokof'ev
  • S. P. Solodovnikov
Brief Communications
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Conclusions

  1. 1.

    The EPR spectra of the anion radicals ofα,α′-azoisobutyrodinitrile and the diethyl ester of azoacetic acid were studied.

     
  2. 2.

    In the formula describing the interaction of the unpaired electron with the nitrogen nucleus, the value of the polarization parameter for the 2s-electrons of the nitrogen atoms, due to the spin density on the nitrogen atom, possesses a value of 9.8 Oe for the sp2-hybridized carbon atom next to the nitrogen, and 5.3 Oe for the sp3-state.

     

Keywords

Nitrogen Ester Carbon Atom Diethyl Nitrogen Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

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Copyright information

© Consultants Bureau 1968

Authors and Affiliations

  • A. I. Prokof'ev
    • 1
  • S. P. Solodovnikov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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