Benzoic acylals

  • M. F. Shostakovskii
  • N. A. Gershtein
  • V. A. Neterman


  1. 1.

    A method was developed for the synthesis of 1-alkylethyl benzoates (acylals) in yields of 80–90% and higher.

  2. 2.

    The following compounds were synthesized for the first time by this method: CH3CH(OR)OCOC6H5, in which R=(CH3)2CH, C4H9, C6H13, C6H11, C6H5, p-CH3C6H4, o-CH3C6H4.

  3. 3.

    Compounds of this type in which R is an alkyl group are unstable to keeping and are extremely sensitive to acid reagents and to heat.

  4. 4.

    Phosphoric oxide is an extremely active catalyst for the polymerization of alkyl vinyl ethers.



Oxide Polymerization Ether Active Catalyst Vinyl 
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Literature cited

  1. [1]
    W. E. Kass, J. Amer. Chem. Soc. 69, 500 (1947).Google Scholar
  2. [2]
    M. F. Shostakovskii, N. A. Gershtein, and V. A. Neterman, Doklady Akad. Nauk SSSR 103. 2, 265 (1955).Google Scholar
  3. [3]
    N. A. Gershtein and M. F. Shostakovskii, Zhur. Obshchei Khim. 18, 1689 (1948).Google Scholar
  4. [4]
    Beilstein, 9, 114 (1926).Google Scholar
  5. [5]
    Beilstein, 9, 113 (1926).Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1960

Authors and Affiliations

  • M. F. Shostakovskii
    • 1
  • N. A. Gershtein
    • 1
  • V. A. Neterman
    • 1
  1. 1.N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSRUSSR

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