Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Synthesis of alkylindans

  • 19 Accesses

  • 1 Citations


  1. 1.

    Reaction between indan and olefins, namely propene and 1-butene, in presence of anhydrous aluminum chloride proceeds with formation of high yields of the corresponding monoand di-alkylmdans substituted in the aromatic nucleus. Under the same conditions isopropylindan and propene give triisopropylindan.

  2. 2.

    Reaction between indan and 2-methyl-2-butene under the same conditions proceeds with much greater difficulty. The yield of the alkylindan is much lower. Higher alkylation products are not formed. Reaction between these hydrocarbons in presence of BF3.H3PO4 as catalyst proceeds analogously.

  3. 3.

    Isopropyl-, diisopropyl-, triisopropyl, sec-butyl-, di-sec-butyl-, and amyl-indans, each having their substituents in the aromatic nucleus, were prepared. With the exception of isopropylindan, all these hydrocarbons were prepared for the first time.

This is a preview of subscription content, log in to check access.

Literature cited

  1. [1]

    J. Entel, C. H. Ruof, and H. C. Howard, Anal. Chem. 26, 3, 612 (1954).

  2. [2]

    W. M. Kutz, J. E. Nickels, J. J. McGovern, and B. B. Corson, J. Amer. Chem. Soc. 70, 4026 (1948).

  3. [3]

    M. S. Carpenter and W. M. Easter, J. Org. Chem. 19, 96 (1954).

  4. [4]

    E. S. Pokrovskaya and T. G. Stepantseva, Doklady Akad. Nauk SSSR 55, 9, 841 (1947).

  5. [5]

    P. Cagniant, A. Deluzarche, and G. Chatelus, Compt. rend. 224, 1064 (1947).

  6. [6]

    A. V. Topchiev, M. V. Kurashov, and Ya. M. Paushkin, Doklady Akad. Nauk SSSR 93, 839 (1953).

  7. [7]

    B. A. Kazanskii, A. F. Plate, and E. M. Terent'eva, Synthesis of Organic Substances [in Russian], Collection II (1952), p. 70.

  8. [8]

    G. Egloff, Physical Constants of Hydrocarbons, (1939) 1, p. 181.

  9. [9]

    J. F. Norris and J. Joubert, J. Amer. Chem. Soc. 49, 885 (1927).

  10. [10]

    I. A. Musaev, Dissertation, Petroleum Inst. Acad. Sci. USSR (1946).

Download references

Author information

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Topchiev, A.V., Pokrovskaya, E.S. & Stepantseva, T.G. Synthesis of alkylindans. Russ Chem Bull 8, 1887–1893 (1959). https://doi.org/10.1007/BF00914762

Download citation


  • Aluminum
  • Chloride
  • Indan
  • Hydrocarbon
  • Propene