Isomeric transformations of 1-tert-butylthiobut-3-yne under the influence of alkali in alcoholic medium

  • E. N. Prilezhaeva
  • G. S. Vasil'ev
  • V. N. Petrov
Brief Communications
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Conclusions

  1. 1.

    The prototropic isomerization of 1-tert-butylthiobut-3-yne (II) has been studied in alcoholic medium at 130° in the presence of alkali.

     
  2. 2.

    The main products of the isomerization are the same compounds that are formed in the isomerization of 1-tert-butyl-thiobuta-2,3-diene (I) and the quantitative composition of the mixtures obtained from sulfides (I) and (II) are somewhat different.

     

Keywords

Sulfide Diene Main Product Quantitative Composition Alcoholic Medium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Literature cited

  1. 1.
    E. N. Prilezhaeva, V. N. Petrov, G. S. Vasil'ev, and A. N. Khudyakova, Izv. Akad. Nauk SSSR, Ser. Khim., 2473 (1969).Google Scholar
  2. 2.
    V. N. Petrov, G. M. Andrianova, and E. N. Prilezhaeva, Izv. Akad. Nauk SSSR, Ser. Khim., 2180 (1966).Google Scholar
  3. 3.
    K. E. Schulter and K. Ph. Reiss, Chem. Ber.,86, 777 (1953).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • E. N. Prilezhaeva
    • 1
  • G. S. Vasil'ev
    • 1
  • V. N. Petrov
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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