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Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides

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Summary

  1. 1.

    It was shown that perfluorovinylmagnesium iodide and perfluorovinylmagnesium bromide can be prepared in yields of 70 and 45%, respectively, in a reaction medium of ether or tetrahydrofuran.

  2. 2.

    A new method was found for the preparation of perfluoroacrylic acid; the method comprises the reaction of CF2=CFMgI with carbon dioxide.

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Literature cited

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    F. Runge, Organomagnesium Compounds, ONTI, 1937.

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    T. Brice et al., J. Amer. Chem. Soc. 68, 968 (1946).

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    R. Haszeldine et al., J. Chem. Soc. 1952, 3423; 1953, 1748; 1954, 1273.

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    J. Park et al., J. Amer. Chem. Soc. 78, 59 (1956).

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    R. Haszeldine. J. Chem. Soc. 1952, 3423.

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    A. Henne and C. Foche, J. Amer. Chem. Soc. 76, 479 (1954).

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    F. Swarts, Bull. Acad. roy. Belgique 34, 307 (1897).

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    J. Park et al., J. Amer. Chem. Soc. 78, 711 (1951).

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Knuniants, I.L., Sterlin, R.N., Iatsenko, R.D. et al. Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides. Russ Chem Bull 7, 1297–1299 (1958). https://doi.org/10.1007/BF00913516

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Keywords

  • Ether
  • Dioxide
  • Carbon Dioxide
  • Bromide
  • Iodide