It was shown that perfluorovinylmagnesium iodide and perfluorovinylmagnesium bromide can be prepared in yields of 70 and 45%, respectively, in a reaction medium of ether or tetrahydrofuran.
A new method was found for the preparation of perfluoroacrylic acid; the method comprises the reaction of CF2=CFMgI with carbon dioxide.
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Knuniants, I.L., Sterlin, R.N., Iatsenko, R.D. et al. Reactions of fluoroolefins Communication 8. Reactions of perfluorovinylmagnesium halides. Russ Chem Bull 7, 1297–1299 (1958). https://doi.org/10.1007/BF00913516
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