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The effect of replacing the carbonyl groups of cyclopentadienylmanganesetricarbonyl by p-donor ligands on the reactivity of the hydrogen atoms of the cyclopentadienylring

  • D. N. Kursanov
  • V. N. Setkina
  • A. G. Ginzburg
  • E. A. Yudkevich
Brief Communications
  • 16 Downloads

Conclusions

  1. 1.

    The replacement of a carbonyl group in CTM by P(C6H5)3, As(C6H5)3 and Sb(C6H5)3 ligands sharply increases the reactivity of the cyclopentadienyl ring in electrophilic hydrogen exchange reactions.

     
  2. 2.

    The effect of the ligands, P(C6H5)3, As(C6H5)3, and Sb(C6H5)3 is transmitted across the manganese atom not only to the carbonyl groups, but also to the cyclopentadienyl ring.

     

Keywords

Hydrogen Manganese Carbonyl Hydrogen Atom Exchange Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

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    A. N. Nesmeyanov, D. N. Kursanov, V. N. Sitkina, N. V. Kislyakova, N. E. Kolobova, and K. N. Anisimov, Izv. Akad. Nauk SSSR, Ser. Khim., 944 (1966).Google Scholar
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Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • D. N. Kursanov
    • 1
  • V. N. Setkina
    • 1
  • A. G. Ginzburg
    • 1
  • E. A. Yudkevich
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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