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Ein Beitrag zur Stereochemie des Arsens in As(III)—Sauerstoffverbindungen

A contribution to the stereochemistry of arsenic in As(III)—Oxygen compounds

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Abstract

The oxygen coordination sphere around As(III) consists of the three primary oxygen atoms (average As−O distance 1.785 Å) and secondary oxygen atoms between 2.70 and 3.37 Å (3.37 Å is the assumed sum of theVan der Waals radii). Reasons are discussed why neither the number (0–3) nor the length of the secondary As−O distances exert an influence on the geometry of the [AsO3]-group and its As−O distances.

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Pertlik, F. Ein Beitrag zur Stereochemie des Arsens in As(III)—Sauerstoffverbindungen. Monatshefte für Chemie 110, 387–392 (1979). https://doi.org/10.1007/BF00911926

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Key words

  • As(III)-oxygen compounds
  • Stereochemistry, As−O